| Title | Season | Episode # | First Aired |
|---|---|---|---|
| A.P.E. Strikes Again | 2 | 1 | 1967-1968 |
| Brainiac's Bubbles | 2 | 8 | 1967-1968 |
| Can a Luthor Change His Spots? Pt. 1 | 3 | 3 | 1968-1969 |
| Can a Luthor Change His Spots? Pt. 2 | 3 | 4 | 1968-1969 |
| Insect Raiders | 1 | 19 | 1966-1967 |
| Lava Men | 1 | 27 | 1966-1967 |
| Luminians on the Loose Pt. 1 | 3 | 11 | 1968-1969 |
| Luminians on the Loose Pt. 2 | 3 | 12 | 1968-1969 |
| Luthor Strikes Again | 1 | 28 | 1966-1967 |
| Luthor's Fatal Fireworks | 2 | 16 | 1967-1968 |
| Luthor's Lethal Laser Pt. 1 | 3 | 1 | 1968-1969 |
| Luthor's Lethal Laser Pt. 2 | 3 | 2 | 1968-1969 |
| Luthor's Loco Looking Glass | 2 | 13 | 1967-1968 |
| Merlin's Magic Marbles | 1 | 4 | 1966-1967 |
| Mermen of Emor | 1 | 2 | 1966-1967 |
| Mission to Planet Peril | 1 | 29 | 1966-1967 |
| Neolithic Nightmare | 1 | 11 | 1966-1967 |
| Night of the Octopod | 2 | 7 | 1967-1968 |
| Rain of Iron Pt. 1 | 3 | 7 | 1968-1969 |
| Rain of Iron Pt. 2 | 3 | 8 | 1968-1969 |
| Return of Warlock | 1 | 20 | 1966-1967 |
| Robot of Riga | 1 | 9 | 1966-1967 |
| Seeds of Disaster | 1 | 34 | 1966-1967 |
| Superman Meets Brainiac | 1 | 33 | 1966-1967 |
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